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Food chains are simple,Food webs are complex
Food chain shows a few interactions ,Food webs show a lot of possible interactions 
Food chain goes in a straight line,Food web all over the place.
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  A food chain is a single line of organisms, where each is preceded by something that it consumes and is followed by something that consumes it. A food web branches out in all directions with arrows pointing from organisms to any number of organisms that consume it.
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