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Well it does not get scatter.Due to dense atmosphere between horizzon and the observer the blue and violet light move away from the horizon.So the light that reaches the observer is mostly red and yellow light.So son appears reddish during sunrise and sunset
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In he early mornimg when the sun is near the horizon the sunlight has to travel a long distance through the atmoshphere to reach us. during this long jpurney most of the blue light of shorter wavelength scatters away and red light with more wavelength reaches us.
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