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 For a given number of carbon atoms, an unbranched alkane has a higher boiling point than any of its branched-chain isomers. This effect is evident upon comparing the boiling points (bp) of selected C 818 isomers.

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Substances consisting entirely of single-bonded carbon and hydrogen atoms and lacking functional groups are called alkanes. There are three basic types of structures that classify the alkanes:

linear straight-chain alkanes
branched alkanes

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