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the pulmonary artery carries blood away from the heart(it is the only artery which carries dexygenated blood)
the pulmonary vein is the vein which carries blood from lungs to heart(it is only vein which carries oxygenated blood)

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Arteries carry blood away from heart and veins carry blood back to the heart
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The Pulmonary artery, Aorta and the Coronary Sinus are main arteries & veins which carry oxygenated blood away from the heart.
The Pulmonary vein,  Superior Vena Cava, Inferior Vena Cava, Ventricles carry deoxygenated blood to the heart.
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