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Solid ammonium carbamate dissociated according to the given reaction NH2COONH4----->2NH3(g)+CO2(g) total pressure of the gas is 5 atm. hence Kp is



LET the total pressure be P atm. and P=5atm
Then partial pressure of NH3 be 2/3P

         partial pressure of CO2 be 1/3P
∴Kp=(P NH3) (P Co2)

=(2/3P)^{2}  (1/3P) =4/27 P^(3)  = 18.5185

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