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Equation of photosynthesis is
6CO2 + 12H2O -------------> C6H12O6 + 6O2 + 6H2O
we take 12 moles of water rather than 6 cause water may sometimes evaporate due to high temparature and if we provide only 6 moles there might be a deficiency in water for photosynthesis. the excess water comes out through transpiration.
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