Question: - From where does the liquid begin to evaporate?
Answer: - In evaporation, the liquid begins to convert into gaseous state from the surface. While in boiling, the liquid begins to change into gaseous state throughout the container.
At what temperature do the both take place at?
Answer: - Evaporation is the changing of a liquid into gaseous state at any temperature, below the boiling point.
Boiling is the conversion of liquid into gaseous state at the boiling point of that substance.

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