The odds are 11:1. (The probability is 1/12.)
Imagine they sat down in age order, with each person randomly picking a seat. The first person is guaranteed to pick a seat that "works". The second oldest can sit to his right or left, since these five can sit either clockwise or counterclockwise. The probability of picking a seat that works is thus 2/4, or 1/2. The third oldest now has three chairs to choose from, one of which continues the progression in the order determined by the second person, for a probability of 1/3. This leaves two seats for the fourth oldest, or a 1/2 chance. The youngest would thus be guaranteed to sit in the right seat, since there is only one seat left. This gives 1 * 1/2 * 1/3 * 1/2 * 1 = 1/12, or 11:1 odds against.